Reversible single-crystal to single-crystal transformations in a Hg(II) derivative. 1D-polymeric chain ⇋ 2D-networking as a function of temperature

Abstract

Reactions of HgX₂ (X = Cl^-, Br^-, l^-) with the ligand hep-H (hep-H = 2-(2-hydroxyethyl)pyridine) in methanol at 298 K result in 1D-polymeric chains of [(X)Hg(μ-X)₂(hep-H)]_∞, 1-3, respectively, where hep-H binds to the Hg(II) ions in a monodentate fashion exclusively with the pyridine nitrogen donor and the suitably ortho-positioned -(CH₂)₂OH group of hep-H remains pendant. The packing diagrams of 1-3 exhibit extensive intramolecular and intermolecular hydrogen bonding interactions leading to hydrogen bonded 2D network arrangement in each case. Though the single crystal of either 2 (X = Br) or 3 (X = I) loses crystallinity upon heating, the single crystal of 1 selectively transforms to a 2D-polymeric network, 4 on heating at 383 K for 1.5 h. The polymeric 4 consists of central dimeric [Hg(μ₃-Cl)(hep-H)Cl]₂ units, which are covalently linked with the upper and lower layers of [-(μ-Cl)₂-Hg-(μ-Cl)₂-Hg(μ-Cl)₂-]_n. The packing diagram of 4 reveals the presence of O-H-Cl and C-H-Cl hydrogen bonding interactions which in effect yields hydrogen bonded 3D-network. Remarkably, the single crystals of 4 convert back to the single crystals of parent 1 on standing at 298 K for three days.