Short synthetic approach towards the triindenotriphenylene (hemifullerene) system

Mehta, G. ; Raghava Sharma, G. V. ; Krishna Kumar, M. A. ; Vedavyasa, T. V. ; Jemmis, E. D. (1995) Short synthetic approach towards the triindenotriphenylene (hemifullerene) system Journal of the Chemical Society, Perkin Transactions 1, 1 (20). pp. 2529-2530. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1995...

Related URL: http://dx.doi.org/10.1039/P19950002529

Abstract

A two-step synthesis of trimethyltribenzotriphenylene 2 from readily available starting materials involving three-fold Wittig reaction and three-fold oxidative photocyclization along a C3-symmetry path is reported. Flash vacuum pyrolysis of 2 in the quest for the triindenotriphenylene (hemifullerene) system has so far led only to the formation of mono-coupled products 6 and 7.

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