Theoretical studies on (μ-S2CR) bridged cyclopentadienyl molybdenum dimers

Prasad, Bharatam V. ; Satyanarayana Reddy, C. ; Jemmis, Eluvathingal D. (1989) Theoretical studies on (μ-S2CR) bridged cyclopentadienyl molybdenum dimers Inorganica Chimica Acta, 162 (2). pp. 281-285. ISSN 0020-1693

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0020-1693(00)83161-8

Abstract

The electronic structures of CpMo(μ-S2C2H2)(μ S2C.S)MoCp, (1), CpMo(μ-S2C2H2)(μ-S2CSMe)- MoCp+ (2) and CpMo(μ-S2C2H2)(μ-S2CCH3)MoCp+ (3) are studied. Electronic factors control the unsymmetrical bridging nature of the η3 bridging units in 2 and 3.

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ID Code:82677
Deposited On:14 Feb 2012 11:19
Last Modified:14 Feb 2012 11:19

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