Kedarnath, G. ; Dey, Sandip ; Jain, Vimal K. ; Dey, Gautam K. ; Varghese, Babu (2006) 2-(N,N-dimethylamino)ethylselenolates of cadmium(II): syntheses, structure of [Cd3(OAc)2(SeCH2CH2NMe2)4] and their use as single source precursors for the preparation of CdSe nanoparticles Polyhedron, 25 (12). pp. 2383-2391. ISSN 0277-5387
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.poly.2006.02.011
Abstract
The reaction of Cd(OAc)2 · 2H2O with NaSeCH2CH2NMe2 gave a homoleptic cadmium selenolate, [Cd(SeCH2CH2NMe2)2]. The latter complex, on treatment with Cd(OAc)2 · 2H2O, afforded [Cd3(OAc)2(SeCH2CH2NMe2)4], which was structurally characterized by single-crystal X-ray diffraction analysis. Pyrolysis of [Cd(SeCH2CH2NMe2)2] either in a mixture of hot hexadecylamine (HDA) and tri-n-octylphosphine oxide (TOPO) or in a furnace (180 and 200 °C) gave CdSe nanoparticles with average sizes varying between 3 and 21 nm. Both cubic and hexagonal phases of CdSe nanoparticles have been isolated under different experimental conditions. The CdSe nanoparticles were characterized by UV-Vis, photoluminescence, X-ray diffraction and electron microscopy. Time resolved luminescence measurements showed three different decay times for both band edge and trap state emissions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cadmium Selenolate; CdSe; Nanoparticles; Crystal Structure; TEM |
| ID Code: | 82307 |
| Deposited On: | 10 Feb 2012 04:48 |
| Last Modified: | 10 Feb 2012 04:48 |
Repository Staff Only: item control page
