Raman spectroscopic investigation of α-glycine at different temperatures

Murli, Chitra ; Thomas, Susy ; Venkateswaran, Sugandhi ; Sharma, Surinder M. (2005) Raman spectroscopic investigation of α-glycine at different temperatures Physica B: Condensed Matter, 364 (1-4). pp. 233-238. ISSN 0921-4526

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.physb.2005.04.020

Abstract

Raman scattering measurements have been carried out on a single crystal of a-glycine in the temperature range 83-360 K. The observed splitting of the NH3+ torsional mode in the temperature range 83-313 K shows that NH3+ torsional motion is non-degenerate even at ambient conditions. The stiffening of the N+H stretch mode on increasing the temperature from 120 to 360 K suggests increase in the inter-layer hydrogen bond length with temperature.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:α-glycine; Raman Spectroscopy; Hydrogen Bond; Low Temperature
ID Code:81878
Deposited On:09 Feb 2012 04:49
Last Modified:09 Feb 2012 04:49

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