Dutt, G. B. ; Periasamy, N. (1991) Electron-transfer distance in intermolecular diffusion-limited reactions Journal of the Chemical Society, Faraday Transactions, 87 (24). pp. 3815-3820. ISSN 0956-5000
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1991...
Related URL: http://dx.doi.org/10.1039/FT9918703815
Abstract
Diffusion-limited fluorescence quenching of ZnTPP(1S1) and quinone (benzoquinone BQ and chloranil CA) have been studied in toluene and acetonitrile at 5, 25 and 45 ° C. The steady-state and time-domain experimental studies indicate that the 'optimum' electron-transfer distance is larger by 3-5 Å for the ZnTPP-CA reaction than that in the ZnTPP-BQ reaction.
Item Type: | Article |
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Source: | Copyright of this article belongs to Royal Society of Chemistry. |
ID Code: | 81716 |
Deposited On: | 07 Feb 2012 11:05 |
Last Modified: | 07 Feb 2012 11:05 |
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