Sangaranarayanan, M. V. ; Rangarajan, S. K. (1981) Microscopic modelling of adsorption and the generalised surface layer hypothesis Canadian Journal of Chemistry, 59 (13). pp. 2072-2079. ISSN 0008-4042
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Official URL: http://www.nrcresearchpress.com/doi/abs/10.1139/v8...
Related URL: http://dx.doi.org/10.1139/v81-302
Abstract
Two- and three-state models for the adsorption of organic compounds at the electrode/electrolyte interface are proposed. Different size requirements, if any, for the neutral molecule and the adsorbing solvent are also considered. It is shown how the empirical, generalised surface layer (GSL) relationship (between the potential difference and the electrode charge) formulated by Damaskin et al. can be understood at the molecular level.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to NRC Research Press. |
| ID Code: | 81257 |
| Deposited On: | 07 Feb 2012 05:04 |
| Last Modified: | 07 Feb 2012 05:04 |
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