Mishra, A. K. ; Bhattacharjee, B. ; Rangarajan, S. K. (1992) Theory of electron transfer processes via chemisorbed intermediates: Part II. Current-potential characteristics Journal of Electroanalytical Chemistry, 331 (1-2). pp. 801-813. ISSN 0022-0728
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-0728(92)85007-P
Abstract
Current-potential characteristics are obtained numerically for a lone-adsorbate-mediated anodic charge transfer at the electrode-solution interface. An increase in the overpotential leads to the appearance of maxima in the anodic current-potential plots instead of the extended activationless region (i.e. a saturation current at large positive overpotentials) predicted by the direct heterogeneous outer-sphere anodic charge transfer process. A detailed analysis of the dependence of current-potential profiles and other kinetic parameters on various system parameters is also presented.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 81219 |
| Deposited On: | 04 Feb 2012 12:38 |
| Last Modified: | 04 Feb 2012 12:38 |
Repository Staff Only: item control page
