Subba Rao, V. V. ; Rao, R. V. G. ; Biswas, A. B. (1965) Thermogravimetric analysis of La, Ce, Pr and Nd oxalates in air and in carbon dioxide atmosphere Journal of Inorganic and Nuclear Chemistry, 27 (12). pp. 2525-2531. ISSN 0022-1902
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-1902(65)80152-X
Abstract
Thermogravimetric analysis of lanthanum, cerium, praseodymium and neodymium oxalates was made in the temperature range 30-1100°C in air and in carbon dioxide. The results indicate that all except cerous oxalate decompose through formation of an intermediate oxycarbonate of the type M2O3·CO2. The decomposition was delayed and sluggish in carbon dioxide, which might be due to delayed nucleation and slow growth rate. Rate parameters have been calculated for dehydration and decomposition.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 81121 |
| Deposited On: | 04 Feb 2012 07:38 |
| Last Modified: | 04 Feb 2012 07:38 |
Repository Staff Only: item control page
