Sen, Asok Chandra ; Chowdhury, Mihir ; Schwartz, Robert W. (1981) Optical activity of rare earth crystals. Europium oxydiacetate Journal of the Chemical Society, Faraday Transactions 2, 77 . pp. 1293-1300. ISSN 0300-9238
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Official URL: http://www.rsc.org/publishing/journals/F2/article....
Related URL: http://dx.doi.org/10.1039/F29817701293
Abstract
The circular dichroism (c.d.) spectra corresponding to 7F0→5D1.2 and 7F1→5D0,1,2 transitions of the europium oxydiacetate crystal are reported. The electric dipole and magnetic dipole contributions to the total transition moment are separated for the principally magnetic dipole allowed 7F0→5D1 transition as well as for the principally electric dipole allowed 7F0→5D2 transition. C.d. spectroscopy is shown to be a particularly sensitive technique for observing 7F1→5D1, 5D2 transitions. A calculation correlating c.d. spectra and structure, the first of its kind for lanthanide complexes, is attempted with the Judd-Ofelt model as basis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 8087 |
| Deposited On: | 25 Oct 2010 11:22 |
| Last Modified: | 04 Feb 2011 04:09 |
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