The effect of bond structure on the Baker-Venkataraman transformation of acetylanisoyloxyindanes and benzoyloxytetrahydroacetonaphthones

O'Farrell, M. P. ; Wheeler, D. M. S. ; Wheeler, M. M. ; Wheeler, T. S. (1955) The effect of bond structure on the Baker-Venkataraman transformation of acetylanisoyloxyindanes and benzoyloxytetrahydroacetonaphthones Journal of the Chemical Society . pp. 3986-3992. ISSN 0368-1769

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1955...

Related URL: http://dx.doi.org/10.1039/JR9550003986

Abstract

Further work on the Banker-Vankataraman transformation in the indane series is described (see Nowlan, Slavin, and Wheeler, J., 1950, 340). A study of this reaction applied to vic,-benzoloxytetrahydroacetonaphthones support the view that the 1 : 2-bond in 5 : 6 : 7 : 8-tetrahydronaphthalene derivatives has a higher order than the 2 : 3-bond. The existance of steric strain in the acetyl group 5 : 6 : 7: 8- tetrahydro-2-hydroxy-1-acetonaphthone is demonstrated and its effects are discussed.

Item Type:Article
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ID Code:80663
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