Deshpande, Sudhindra H. ; Kelkar, Ashutosh A. ; Gonnade, Rajesh G. ; Shingote, Savita K. ; Chaudhari, Raghunath V. (2010) Catalytic asymmetric transfer hydrogenation of ketones using [Ru(p-cymene)Cl2]2 with chiral amino alcohol ligands Catalysis Letters, 138 (3-4). pp. 231-238. ISSN 1011-372X
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Official URL: http://www.springerlink.com/content/n23x413r74k433...
Related URL: http://dx.doi.org/10.1007/s10562-010-0408-y
Abstract
Catalytic asymmetric transfer hydrogenation of aromatic alkyl ketones has been investigated using [Ru(p-cymene)Cl2]2 and new derivatives of β-amino alcohols synthesized from (S)-(-)-lactic acid and mandelic acid as ligands. Chiral secondary alcohols were obtained with good to excellent conversion (60-90%) and moderate to good enantioselectivities (40-86%).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| Keywords: | Asymmetric Transfer Hydrogenation; Ru Catalyst; Ketones; Amino Alcohol Ligand |
| ID Code: | 8063 |
| Deposited On: | 25 Oct 2010 10:13 |
| Last Modified: | 28 May 2011 09:45 |
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