Kelkar, Ashutosh A. ; Kolhe, Devidas S. ; Chaudhari, Raghunath V. (1992) Carbonylation of methanol to acetic acid using homogeneous Ru complex catalyst Journal of Organometallic Chemistry, 430 (1). pp. 111-116. ISSN 0022-328X
Full text not available from this repository.
Official URL: http://dx.doi.org//10.1016/0022-328X(92)80101-3
Related URL: http://dx.doi.org/10.1016/0022-328X(92)80101-3
Abstract
Carbonylation of methanol to give acetic acid catalysed by Ru complexes such as trans-Ru(CO)2Cl2(PPh3)2, cis-Ru(CO)2Cl2(PPh3)2 and H2Ru(CO)(PPh3)3 is reported. The highest activity and selectivity were obtained with H2Ru(CO)(PPh3)3 as the catalyst precursor. Hydrogen increases the activity and selectivity of catalysts such as trans-Ru(CO)2Cl2(PPh3)2, cis-Ru(CO)2Cl2(PPh3)2, but has no influence on the activity and selectivity in the case of H2Ru(CO)(PPh3)3.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 8040 |
| Deposited On: | 25 Oct 2010 10:01 |
| Last Modified: | 30 May 2011 04:44 |
Repository Staff Only: item control page
