Khan, Faiz Ahmed ; Sudheer, Ch. (2009) Ruthenium-mediated oxidation under buffered conditions: a simple and useful protocol for the synthesis of norbornyl α-diketones with acid sensitive functionalities Advanced Synthesis & Catalysis, 351 (6). pp. 939-944. ISSN 1615-4150
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...
Related URL: http://dx.doi.org/10.1002/adsc.200900042
Abstract
The supported ruthenium-catalyzed oxidation of the 1,2-dihaloalkene moiety in tetrahalonorbornyl derivatives possessing acid labile functionalities to afford the corresponding α-diketones is demonstrated. The protocol was successfully applied in the synthesis of a cyclopenta-annulated δ-lactone derived from D-mannitol.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Diels-Alder Reaction; α-diketones; δ-lactones; Oxidation; Ruthenium; Supported Catalysts |
| ID Code: | 80352 |
| Deposited On: | 31 Jan 2012 14:29 |
| Last Modified: | 31 Jan 2012 14:29 |
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