Khan, Faiz Ahmed ; Upadhyay, Sarasij K. (2009) Synthesis and electrochemical signature of novel norbornyl-ferrocene hybrids Synthesis, 2009 (16). pp. 2773-2777. ISSN 0039-7881
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-0029-1217601
Abstract
Novel norbornyl-ferrocene hybrids have been synthesized in excellent yields via Diels-Alder reactions between 1,2,3,4-tetrahalo-5,5-dimethoxycyclopentadiene and vinyl- or acryloylferrocenes. Halogen reduction of vinylferrocene adducts followed by catalytic hydrogenation afforded ferrocenyl-norbornane. Hybrids showed the dependence of the redox potential on the nature of the substituents on the norbornyl moiety.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Diels-Alder Reaction; Ferrocene; Radical Hydrodehalogenation; Reduction; Electrochemical Study |
| ID Code: | 80348 |
| Deposited On: | 31 Jan 2012 14:29 |
| Last Modified: | 31 Jan 2012 14:29 |
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