Khan, Faiz Ahmed ; Upadhyay, Sarasij K. (2008) A stereoselective C7nC5x free-radical cascade route to optically pure and potentially useful tetracyclic amines Tetrahedron Letters, 49 (42). pp. 6111-6114. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2008.08.013
Abstract
Nucleophilic racemic amines have been synthesized utilizing a C7nC5x free-radical cascade reaction from a bis-allyl amine starting material. Being potentially useful organocatalytic bases as is evident from their screening in the Baylis-Hillman reaction, optically pure amines were also synthesized from optically pure aldehydes (−) or (+)-4. Bis-allyl amides under similar radical reaction condition resulted in C7n cyclized products.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 80333 |
| Deposited On: | 31 Jan 2012 14:29 |
| Last Modified: | 31 Jan 2012 14:29 |
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