Total synthesis of (±) - pentenomycin

Khan, Faiz Ahmed ; Rout, Bhimsen (2006) Total synthesis of (±) - pentenomycin Tetrahedron Letters, 47 (30). pp. 5251-5253. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.05.156

Abstract

A concise stereoselective route to (±)-pentenomycin 1 in 33% overall yield starting from the readily accessible Diels-Alder adduct 4 is reported. The key reaction involves decarbonylation of β-methoxy-α,β-unsaturated aldehyde 8 obtained from β-hydroxy-dimethylketal 6.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:80330
Deposited On:31 Jan 2012 14:27
Last Modified:31 Jan 2012 14:27

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