Origin of graphite, and temperature of metamorphism in Precambrian Eastern Ghats Mobile Belt, Orissa, India: a carbon isotope approach

Abstract

The carbon isotope composition of graphite and carbon and oxygen isotope composition of associated calcite from different locations of the Eastern Ghats Mobile Belt (EGMB) of Orissa have been measured in order to understand the origin of graphite. The δ¹³C values of graphite range from -2.4‰ to -26.6‰. Forty-four of sixty-one samples have δ¹³C values less than -20‰. Most of these low δ¹³C values graphite corresponds to schists and disseminations in khondalite and calc-silicate granulites, thus indicating graphitization of organic matter. The remaining light-carbon-graphite occurs as veins which is the result of graphitization of transported organic matter. The graphite with intermediate δ¹³C value (-13‰ to -19‰) indicates carbon contributions from both organic and carbonates sources and/or mantle sources. The higher δ¹³C values graphite (-2.4‰ to -8.8‰) represent mantle carbon and/or carbonate sources without significant contribution from organic carbon. The temperatures of metamorphism have been estimated using carbon isotope ratios of graphite and associated calcite of calc-silicate granulites, where typical cation exchange thermometer assemblages are lacking and significant mineral reaction textures used to calculate pressure-temperature of metamorphic events are absent. Metamorphic temperatures obtained 945°C are close to the ultrahigh-temperature reported from the EGMB. The minimum temperature estimated using the graphite-carbonate carbon isotope ratio is 90°C. The lower estimates of temperatures probably indicate changes in the carbon isotope ratio of calcite by decarbonation reaction or armoring of carbonaceous matter in silicates during metamorphism preventing continuous exchange with calcite.