Wismach, Cathleen ; du Mont, Wolf-Walther ; Jones, Peter G. ; Ernst, Ludger ; Papke, Ulrich ; Mugesh, Govindasamy ; Kaim, Wolfgang ; Wanner, Matthias ; Becker, Klaus D. (2004) Selenol nitrosation and Se-nitrososelenol homolysis: a reaction path with possible biochemical implications Angewandte Chemie International Edition, 43 (30). pp. 3970-3974. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200453872
Abstract
The nitrosation of selenol 1 with an alkyl nitrite (see scheme) at -78°C generated the first Se-nitrososelenol 2, which was identified by IR spectroscopy and further proven by its 1,4-addition to dimethylbutadiene. Compound 2 decomposes rapidly to give 3. The experiments may give insight into the interactions of selenoproteins with NO in vivo.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Bioinorganic Chemistry; Nitrogen Oxides; Nitrosation; Oximes; Selenium |
| ID Code: | 79335 |
| Deposited On: | 25 Jan 2012 06:05 |
| Last Modified: | 25 Jan 2012 06:05 |
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