Patil, R. P. ; Kelkar, A. A. ; Chaudhari, R. V. (1988) Carbonylation of ethanol using homogeneous ir complex catalyst: effect of ligands and reaction conditions Journal of Molecular Catalysis, 47 (1). pp. 87-97. ISSN 0304-5102
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/030451...
Related URL: http://dx.doi.org/10.1016/0304-5102(88)85076-4
Abstract
Carbonylation of ethanol using IrCl3 · 3H2O as catalyst precursor with HI as a promoter is reported. The role of N- and P-containing ligands and solvents, and the influence of reaction conditions on the activity and selectivity is discussed. The average activity vs. HI concentration showed an unusual trend with a maximum. The water-gas shift reaction was found to be significant above 483 K and at higher concentrations of HI (»1.12 × 10-3 mol cm-3).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7922 |
| Deposited On: | 25 Oct 2010 09:13 |
| Last Modified: | 30 May 2011 04:55 |
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