Transition metal-saccharide chemistry: synthesis, characterization and solution stability studies of cis-dioxomolybdenum saccharide complexes

Mukhopadhyay, Anindita ; Karkamkar, Abhijeet ; Kolehmainen, Erkki ; Rao, Chebrolu P. (1998) Transition metal-saccharide chemistry: synthesis, characterization and solution stability studies of cis-dioxomolybdenum saccharide complexes Carbohydrate Research, 311 (3). pp. 147-154. ISSN 0008-6215

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0008-6215(98)00186-4

Abstract

Six cis-dioxomolybdenum(VI) complexes of simple monosaccharides (D-glucose, D-fructose, D-galactose, D-mannose, D-ribose and D-xylose) have been synthesized and characterized by a variety of analytical and spectral methods. Both the solution and solid-state studies have supported the presence of dimeric structures, formed through the cis-MoO2 moieties and the bridging saccharide units. Solution stability of these complexes as a function of time has also been addressed.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Transition Metal-saccharide Chemistry; cis-Dioxomolybdenum Saccharides; Solution Stability; Dimeric Structure; Bridging Saccharide Units
ID Code:79208
Deposited On:24 Jan 2012 15:21
Last Modified:19 Apr 2012 05:44

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