Dey, Mishtu ; Chinta, Jugun Prakash ; Long, Gary J. ; Rao, Chebrolu P. (2009) Synthesis and characterization of complexes of Fe(III), Co(III), Ni(II), Cu(II), Zn(II) and UO22+ with p-tert-butylcalix[4]arene bearing two imine pendants linked through salicylyl moiety at the lower rim Indian Journal of Chemistry - Section A: Inorganic, Physical, Theoretical and Analytical Chemistry, 48 . pp. 1484-1491. ISSN 0376-4710
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Abstract
Metal ion complexes of the double-armed p-tert-butylcalix[4]arene derivative possessing imine functionality linked through salicylyl moiety at the lower rim has been synthesized for the first time and characterized by analytical, spectral and magnetic methods. The 1, 3- di-calix[4]arene-imine conjugate exhibits variable coordination behavior, from tetradentate to hexadentate, depending upon the metal ion to which it is bound, by always acting as di-anionic. While it uses both the ether oxygens of the pendants to coordinate in the case of Fe(III), Co(III) and Ni(II) complexes, it uses only the pendant salicylidene moieties in the case of Cu(II) and Zn(II) complexes. The Zn(II) complex catalysis ester hydrolysis through the formation of Zn(II)-hydroxo species.
Item Type: | Article |
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Source: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
Keywords: | Coordination Chemistry; Calixarenes; Calix[4]arene-imine Conjugates; Iron; Cobalt; Nickel; Copper; Zinc; Uranium; FAB Mass Spectrometry; Magnetic Susceptibility; Electron Paramagnetic Resonance; Mossbauer Spectroscopy |
ID Code: | 79186 |
Deposited On: | 24 Jan 2012 15:29 |
Last Modified: | 18 May 2016 21:39 |
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