Four-, five- and six-coordinated ZnII complexes of OH-containing ligands: syntheses, structure and reactivity

Dey, Mishtu ; Rao, Chebrolu Pulla ; Saarenketo, Pauli ; Rissanen, Kari ; Kolehmainen, Erkki (2002) Four-, five- and six-coordinated ZnII complexes of OH-containing ligands: syntheses, structure and reactivity European Journal of Inorganic Chemistry, 2002 (8). pp. 2207-2215. ISSN 1434-1948

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1099-06...

Related URL: http://dx.doi.org/10.1002/1099-0682(200208)2002:8<2207::AID-EJIC2207>3.0.CO;2-N

Abstract

Four-, five- and six-coordinated complexes of ZnII with OH-rich molecules possessing an ONO binding core were synthesized, characterized and their structures were established by single-crystal X-ray diffraction. The corresponding metal ion geometries were found to be distorted tetrahedral, square pyramidal and octahedral, respectively. The complexes exhibit interesting lattice structures such as layered and corrugated sheets owing to the presence of a number of weak intermolecular interactions. The five-coordinated, water-bound ZnII complex was studied because of its putative hydrolysis property towards p-nitrophenyl acetate.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:N,O Ligands; X-ray Diffraction; Hydrogen Bonds; Metalloenzymes; Zinc
ID Code:79181
Deposited On:24 Jan 2012 15:24
Last Modified:19 Apr 2012 06:00

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