Bandwar, Rajiv P. ; Srinivasa Raghavan, M. S. ; Rao, Chebrolu P. (1995) Transition metal-saccharide chemistry: D-glucose complexes of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) BioMetals, 8 (1). pp. 19-24. ISSN 0966-0844
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Official URL: http://www.springerlink.com/content/k216n126043362...
Related URL: http://dx.doi.org/10.1007/BF00156153
Abstract
Metal complexes of D-glucose (D-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt4]2[MBr2Cl2] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(D-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| Keywords: | Co(II); Complexes; Cu(II); Glucose; Mn(II); Ni(II); Saccharide; Transition Metal; Zn(II) |
| ID Code: | 79121 |
| Deposited On: | 24 Jan 2012 15:19 |
| Last Modified: | 19 Apr 2012 05:40 |
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