Patil, Nandkumar M. ; Kelkar, Ashutosh A. ; Chaudhari, Raghunath V. (2004) Synthesis of triarylamines by copper-catalyzed amination of aryl halides Journal of Molecular Catalysis A: Chemical, 223 (1-2). pp. 45-50. ISSN 1381-1169
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13811...
Related URL: http://dx.doi.org/10.1016/j.molcata.2003.09.038
Abstract
A simple and efficient methodology for the synthesis of triphenylamine (TPA) in a single step has been demonstrated using copper catalyst with a ligand. The effect of parameters such as catalyst precursors, ligands, bases and solvents on activity and selectivity to triphenylamine were studied at 115 °C. Best results were obtained using 2,6-diphenylpyridine as a ligand (94% yield of TPA).
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Amination; Copper Catalyst; Triphenylamine; Arylamines |
ID Code: | 7905 |
Deposited On: | 25 Oct 2010 09:19 |
Last Modified: | 28 May 2011 11:14 |
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