Synthesis of triarylamines by copper-catalyzed amination of aryl halides

Patil, Nandkumar M. ; Kelkar, Ashutosh A. ; Chaudhari, Raghunath V. (2004) Synthesis of triarylamines by copper-catalyzed amination of aryl halides Journal of Molecular Catalysis A: Chemical, 223 (1-2). pp. 45-50. ISSN 1381-1169

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13811...

Related URL: http://dx.doi.org/10.1016/j.molcata.2003.09.038

Abstract

A simple and efficient methodology for the synthesis of triphenylamine (TPA) in a single step has been demonstrated using copper catalyst with a ligand. The effect of parameters such as catalyst precursors, ligands, bases and solvents on activity and selectivity to triphenylamine were studied at 115 °C. Best results were obtained using 2,6-diphenylpyridine as a ligand (94% yield of TPA).

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Amination; Copper Catalyst; Triphenylamine; Arylamines
ID Code:7905
Deposited On:25 Oct 2010 09:19
Last Modified:28 May 2011 11:14

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