Absorption and fluorescence in frequency-modulated fields under conditions of strong modulation and saturation

Abstract

The dynamical behavior of a two-level system in an intense frequency-modulated field is obtained without recourse to the weak-modulation assumption. Solutions to the optical Bloch equations are expressed in terms of continued fractions involving 2×2 matrices. Such matrix-continued fractions are numerically evaluated to obtain a wide variety of absorption and fluorescence spectra in frequency-modulated fields. Results in various special cases involving combinations of weak fields, weak modulation, strong modulation, and strong fields are given. Analytical results for weak fields but with an arbitrary degree of modulation are also presented. The spectra exhibit additional resonances for strong modulation. The main resonance shifts and broadens considerably due to strong modulation and saturation effects.