Phase behaviour of the discotic mesogen 2,3,6,7,10,11-hexahexylthiotriphenylene (HHTT) under hydrostatic pressure

Abstract

The phase behaviour of the discotic mesogen 2,3,6,7,10,11-hexahexylthiotriphenylene (HHTT) was investigated under hydrostatic pressures up to 500 MPa using high pressure optical and DTA measurements. The known enantiotropic phase transitions of HHTT, i.e. crystal (Cr)-helical phase (H), H-hexagonal columnar phase (Col_h) and Col_h-isotropic liquid (I) were observed up to 32 MPa. Application of hydrostatic pressures above 32 MPa results in the H and Col_h phases becoming monotropic, depending upon the applied pressure. The H phase was observed as a monotropic phase in the pressure region between 32 and about 180 MPa. Thus, the I MCol_h MH MCr transition sequence appeared only on cooling under these pressures, while the Cr MCol_h MI transition occurred on heating. Further increases in pressure above a second limiting value leads to the Col_h phase becoming monotropic. Thus the I MCol_h MCr transition sequence appeared on cooling, while the Cr MI transition was observed on heating. The T vs. P phase diagram based on the data obtained in the heating mode contains two triple points; one is estimated as 40 MPa, 77.2° C for the Cr-H-Col_h triple point and the other is extrapolated as 285 MPa, 118.3° C for the Cr-Col_h-I triple point. These triple points define the upper limits for the appearance of the stable H and Col_h phases, respectively.