Mandal, S. ; Bharadwaj, P. K. (1992) Hexa-coordinated copper(II) complexes having CuN2S*2S2 (S* = thioether) chromophore: synthesis, electrochemistry and spectroscopy Polyhedron, 11 (9). pp. 1037-1042. ISSN 0277-5387
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)84471-X
Abstract
Four stable, neutral hexa-coordinated copper(II) complexes with the N2S*2S2 (S* = thioether) donor set have been isolated in the solid state. A dichloro complex of copper(II) has also been prepared with the chromophore CuN2S*2Cl2, where the two thiolates are replaced by two chlorides. These complexes have tetragonal coordination geometry around copper(II) with g| > ghu > ge and A| values within 101-115 G in acetonitrile glass, and show an intense absorption band around 600 nm attributable to thiolate → copper(II) LMCT transition. In acetonitrile the complexes show well-defined cyclic responses in their cyclic voltammograms at room temperature.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 78709 |
| Deposited On: | 23 Jan 2012 03:49 |
| Last Modified: | 23 Jan 2012 03:49 |
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