Aijaz, Arshad ; Carolina Sañudo, E. ; Bharadwaj, Parimal K. (2009) A dicarboxylate with asymmetric coordination ability: characterization of a two dimensional coordination polymer of copper(II) exhibiting spin canting Inorganica Chimica Acta, 362 (11). pp. 4246-4250. ISSN 0020-1693
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.ica.2009.05.054
Abstract
A copper(II) coordination polymer {[Cu2(cpa)2]}n (1) (cpaH2 = 4-carboxyphenoxyacetic acid) has been synthesized by hydrothermal technique. The X-ray structure of the compound shows that it is a 2D coordination polymer where Cu(II) ions are pentacoordinated in a square pyramidal fashion. The magnetic measurement of 1 in different magnetic fields suggest a weak ferromagnetic ordering taking place below 20 K, arising from spin canting phenomenon due to the non-coplanar basal planes of copper ions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Coordination Polymer; Carboxylate; Magnetism; Spin Canting |
| ID Code: | 78697 |
| Deposited On: | 23 Jan 2012 03:57 |
| Last Modified: | 23 Jan 2012 03:57 |
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