Chaudhari, Raghunath V. ; Doraiswamy, L. K. (1974) Simultaneous absorption and reaction of two gases in a liquid/formation of ethyl chloride from ethylene and hydrogen chloride Chemical Engineering Science, 29 (2). pp. 349-354. ISSN 0009-2509
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/000925...
Related URL: http://dx.doi.org/10.1016/0009-2509(74)80043-6
Abstract
The simultaneous absorption of ethylene and hydrogen chloride with chemical reaction in a medium of nitrobenzene containing dissolved catalyst (aluminium chloride) was studied. The experimental results indicated that the absorption occurs in the kinetic regime. The reaction was found to be first-order with respect to the reactants (ethylene and hydrogen chloride) as well as the catalyst. The rate constants calculated were 1.16×105, 2.80×105, 6.11×105 and 1.44×106 [cm3/g mole]2/sec at 30, 40, 50 and 60°C respectively and the activation energy 16600 cal/g mole.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7862 |
| Deposited On: | 25 Oct 2010 08:46 |
| Last Modified: | 30 May 2011 06:14 |
Repository Staff Only: item control page
