Das, Amitava ; Bajaj, Hari C. ; Chatterjee, Debabrata (1994) Kinetics and mechanism of substitution of [RuIII(Hedtra)(H2O)] (Hedtra = N-hydroxyethylethylenediaminetriacetate) with iodide ion in aqueous solution Transition Metal Chemistry, 19 (1). pp. 111-112. ISSN 0340-4285
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Official URL: http://www.springerlink.com/content/q702686306706g...
Related URL: http://dx.doi.org/10.1007/BF00166282
Abstract
The interaction of iodide ion with [RuIII(Hedtra)(H2O)] (Hedtra = N-hydroxyethylethylenediaminetriacetate) was investigated by spectrophotometry, electrochemical and stopped-flow techniques. The rate of formation of a red [RuIII(Hedtra)I]- complex was found to be first order both with respect to [RuIII(Hedtra)(H2O)] and [I-]. Rate and activation parameters are consistent with the proposed associative interchange mechanism. Experimental results are discussed with reference to the data available for other ligand substitutions of the [RuIII(Hedtra)(H2O)] complex.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 78528 |
| Deposited On: | 20 Jan 2012 04:19 |
| Last Modified: | 20 Jan 2012 04:19 |
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