Shukla, Atindra D. ; Bajaj, H. C. ; Das, Amitava (2001) β-cyclodextrin-assisted intervalence charge transfer in mixed-valent [2]rotaxane complexes having metal centers linked by an interrupted β-electron system Angewandte Chemie International Edition, 40 (2). pp. 446-448. ISSN 1433-7851
Full text not available from this repository.
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...
Related URL: http://dx.doi.org/10.1002/1521-3773(20010119)
Abstract
FeII to RuIIIelectron transfer is initiated by the inclusion of saturated bridging ligands into the β -cyclodextrin (CD) cavity of [2]rotaxane complexes and is observed as an intervalence charge transfer (IVCT) band in the electronic spectra (see picture). The rotaxanes are synthesized by using RuIII and FeII complexes as stoppers, β -CD as the cyclic molecular head, and 4,4'-bipyridine derivatives with interrupted π-electron system as the bridging ligand between the metal centers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Cyclodextrins; Inclusion Compounds; Metal-metal Interactions; Mixed-valent Compounds; Rotaxanes |
| ID Code: | 78526 |
| Deposited On: | 20 Jan 2012 04:19 |
| Last Modified: | 20 Jan 2012 04:19 |
Repository Staff Only: item control page
