Bajaj, H. C. ; Shukla, Atindra D. ; Das, Amitava (2002) Intervalence charge transfer transition in mixed valence complexes synthesised from RuIII(edta)- and FeII(CN)5-cores Proceedings of the Indian Academy of Sciences - Chemical Sciences, 114 (4). pp. 431-442. ISSN 0253-4134
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Abstract
Intervalence charge transfer properties were studied for a set of mixed valence complexes incorporating Ru(III) and Fe(II)-centres linked by various saturated and unsaturated bridging ligands (BL). Studies reveal that degree of ground state electronic interaction and coupling between Ru(III) and Fe(II)-centres can be attenuated by changing the nature of the bridging ligand. Further, inclusion of the bridging ligand with interrupted π-electron system in a β-CD cavity initiate an optical electron transfer from Fe(II) to Ru(III) which is otherwise not observed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Mixed Valence Complexes; Intervalence Charge Transfer; Rotaxane; Inclusion Complex; Optical Electron Transfer; Cyclodextrin |
| ID Code: | 78522 |
| Deposited On: | 20 Jan 2012 04:20 |
| Last Modified: | 18 May 2016 21:18 |
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