Divekar, S. S. ; Bhanage, B. M. ; Deshpande, R. M. ; Gholap, R. V. ; Chaudhari, R. V. (1994) Selectivity in hydroformylation of 1-decene by homogeneous catalysis Journal of Molecular Catalysis, 91 (1). L1-L6. ISSN 0304-5102
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/030451...
Related URL: http://dx.doi.org/10.1016/0304-5102(94)00045-X
Abstract
The selectivity in the hydroformylation of 1-decene by homogeneous catalysis with HRh-(CO) (PPhf3)3 was studied. Aromatic solvents (benzene, toluene) gave total selectivity to aldehyde products, but alcoholic solvents gave higher n/iso ratios. The presence of an excess of phosphine also led to improved n/iso ratios.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Hydroformylation; Olefins; Selectivity |
| ID Code: | 7843 |
| Deposited On: | 25 Oct 2010 10:09 |
| Last Modified: | 30 May 2011 04:38 |
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