Thomas, Anitha M. ; Mandal, Gagan C. ; Tiwary, Satish K. ; Rath, Rakesh K. ; Chakravarty, Akhil R. (2000) Ascorbate oxidation leading to the formation of a catalytically active oxalato bridged dicopper(II) complex as a model for dopamine β-hydroxylase Journal of the Chemical Society, Dalton Transactions, 2000 (9). pp. 1395-1396. ISSN 0300-9246
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2000...
Related URL: http://dx.doi.org/10.1039/B001055N
Abstract
A dicopper(II) complex [Cu2(bpy)2(μ-ox)]X2 (X=ClO4−, PF6−; ox=C2O42-) has been found to be catalytically active in the oxidation of ascorbic acid by dioxygen involving a copper(I) intermediate species and the process is also effective in the presence of benzylamine to form benzaldehyde.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 78239 |
| Deposited On: | 18 Jan 2012 10:53 |
| Last Modified: | 18 Jan 2012 10:53 |
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