Deshpande, Raj M. ; Mahajan, Avinash N. ; Diwakar, Makarand M. ; Ozarde, Prakash S. ; Chaudhari, R. V. (2004) Chemoselective hydrogenation of substituted nitroaromatics using novel water-soluble iron complex catalysts Journal of Organic Chemistry, 69 (14). pp. 4835-4838. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo035511t
Related URL: http://dx.doi.org/10.1021/jo035511t
Abstract
Chemoselective hydrogenation of substituted nitroaromatic compounds by water-soluble iron complex catalysts with molecular hydrogen has been reported for the first time. This biphasic catalyst presents an opportunity for a solvent-free hydrogenation. This catalyst system provides a low-cost, efficient alternative to the selective but environmentally unacceptable stoichiometric reductions as well as the supported noble metal catalysts used for hydrogenation. An efficient recycling strategy has resulted in a cumulative turnover number above 6000.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 7757 |
| Deposited On: | 25 Oct 2010 10:36 |
| Last Modified: | 28 May 2011 11:08 |
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