Nair, V. S. ; Bhanage, B. M. ; Deshpande, R. M. ; Chaudhari, R. V. (1998) Kinetics in biphasic catalysis using ethylene glycol as a co-solvent in the hydroformylation of 1-hexene Studies in Surface Science and Catalysis, 113 . pp. 529-539. ISSN 0167-2991
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S01672...
Related URL: http://dx.doi.org/10.1016/S0167-2991(98)80328-5
Abstract
An investigation on the kinetic aspects of hydroformylation of 1-hexene using water soluble Rh-TPPTS complex catalyst in a biphasic medium using ethylene glycol as a co- solvent is presented. The effect of reaction parameters such as, partial pressure of CO, partial pressure of hydrogen and olefin concentration on the activity were studied at 353, K. A kinetic model has also been proposed to predict the observed rate data. Condensation of heptanals with ethylene glycol led to the formation of acetal derivatives, which were isolated and characterised.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7749 |
| Deposited On: | 25 Oct 2010 10:37 |
| Last Modified: | 30 May 2011 04:17 |
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