Rajadurai, S. ; Bhattacharyya, K. ; Das, P. K. (1986) Nickelocene: a Universal quencher of organic triplets Chemical Physics Letters, 129 (3). pp. 244-252. ISSN 0009-2614
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(86)80205-6
Abstract
Organic triplets, with energies in the range 0.9-3.2 eV, are quenched by nickelocene with rate constants in the limit of diffusion control ((1.3-11) × 109 M-1s-1 in benzene). The efficient quenching, explainable in terms of a combination of energy and electron transfer, suggests the existence of a low-lying spin-forbidden transition (< 0.9 eV) in nickelocene.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 77191 |
| Deposited On: | 10 Jan 2012 07:42 |
| Last Modified: | 10 Jan 2012 07:42 |
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