Addition compounds of thionyl halides with tertiary amines

Paul, R. C. ; Khurana, H. ; Vasisht, S. K. ; Chadha, S. L. (1969) Addition compounds of thionyl halides with tertiary amines Zeitschrift für Anorganische und Allgemeine Chemie, 370 (3-4). pp. 185-190. ISSN 0044-2313

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.19...

Related URL: http://dx.doi.org/10.1002/zaac.19693700310

Abstract

Thionyl chloride and bromide react with pyridine, β- and γ-picoline, quinoline, isoquinoline and piperidine giving rise to addition compounds having 1:2 stoichiometry (thionyl halide: base). Infrared spectral data regarding the complexes formed indicate the coordination of the base molecule through its nitrogen atom to the sulphur atom of thionyl halide.

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