Oxozirconium(IV) alkoxides

Paul, Ram Chand ; Gupta, Surinder Kumar ; Goyal, Veena ; Vasisht, Sham Kumar (1977) Oxozirconium(IV) alkoxides Monatshefte für Chemie / Chemical Monthly, 108 (5). pp. 1019-1025. ISSN 0026-9247

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Official URL: http://www.springerlink.com/content/kr732721543703...

Related URL: http://dx.doi.org/10.1007/BF00897682

Abstract

Oxozirconium(IV) alkoxides of the type ZrO(OR)2·ROH and ZrOCl(OR)·2ROH, where R is methyl, ethyl, and isopropyl, and ZrO(OCMe3)2·0.5Me3COH and ZrOCl(OCMe3)·1.5Me3COH have been prepared by the reaction of dichloroxozirconium(IV)-2-acetic acid with corresponding alcohols in the presence of appropriate amounts of piperidine. The alkoxides have been isolated and characterised through infrared, thermal and conductance studies.

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