Paul, R. C. ; Sharma, R. ; Puri, T. ; Kapoor, R. (1977) Formic acid solvent system. II. Conductance and solvation studies of 1:1 electrolytes in formic acid Australian Journal of Chemistry, 30 (3). pp. 535-541. ISSN 0004-9425
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Official URL: http://www.publish.csiro.au/paper/CH9770535.htm
Related URL: http://dx.doi.org/10.1071/CH9770535
Abstract
Conductances of some 1:1 electrolytes have been measured in the concentration range (5-100)×10−3 mol l−1 in anhydrous formic acid at 25°. The conductance data have been analysed by Fuoss-Shedlovsky equations. Transference numbers of sodium and potassium formates have been measured in this solvent at 25° by a modified Hittorf's method in the concentration range (3-80)×mol l-1. Ionic mobilities, effective ionic radii and solvation numbers of various ions in solution have been calculated. Solvation of cations decreases with the increase in the crystal radii of the ions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Commonwealth Scientific and Industrial Research Organisation Publishing. |
| ID Code: | 77088 |
| Deposited On: | 09 Jan 2012 14:28 |
| Last Modified: | 09 Jan 2012 14:28 |
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