Solution chemistry in substituted sulphuric acid. III. Behaviour of acid anhydrides in fluorosulphuric acid

Paul, Ram Chand ; Sharma, S. K. ; Sharma, R. D. ; Paul, K. K. ; Malhotra, K. C. (1971) Solution chemistry in substituted sulphuric acid. III. Behaviour of acid anhydrides in fluorosulphuric acid Journal of Inorganic and Nuclear Chemistry, 33 (9). pp. 2905-2911. ISSN 0022-1902

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-1902(71)80052-0

Abstract

Oxides of nitrogen form nitronium and nitrosyl ions when dissolved in fluorosulphuric acid. Nitronium and nitrosyl fluorosulphates have been isolated and characterised. Phosphorous pentoxide forms a mixture of disulphuryl and trisulphuryl fluoride. Oxides of arsenic antimony and bismuth form fluorosulphates. Sulphur trioxide forms pyrofluorosulphuric acid when mixed with fluorosulphuric acid, whereas selenium trioxide forms a mixture of compounds. Anhydrides of organic acids behave as weak bases in fluorosulphuric acid.

Item Type:Article
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Deposited On:09 Jan 2012 14:21
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