Paul, Ram Chand ; Kapoor, Pratibha ; Kapoor, Ramesh ; Verma, Rajendar Dev (1980) Chemistry of imidobis (sulphuryl chloride). VI. Behaviour of electrolytes in imidobis (sulphuryl chloride) Journal of Inorganic and Nuclear Chemistry, 42 (1). pp. 9-11. ISSN 0022-1902
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-1902(80)80034-0
Abstract
Bases constitute the largest class of electrolytes in imidobis (sulphuryl chloride) because of its highly acidic nature. Alkali metal salts, MN(SO2Cl)2 (where M=Na, K and Rb) behave as ansolvobases whereas solutes containing oxygen, nitrogen or phosphorus donor atoms behave as solvobases. Electrolytes such as CH3CO2H, CHCl2CO2H, CF3CO2H, HCl, CH3SO3H, p-CH3C6H4SO3H and H2SO4 which behave as acids in aqueous solutions behave as solvobases of this solvent. HSO3F behaves as ansolvoacid and SnCl4 and SbCl5 as solvoacids of this solvent system. Adducts of a few monocarboxylic acids with HN(SO2Cl)2 have been isolated and characterized.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 77059 |
| Deposited On: | 09 Jan 2012 14:29 |
| Last Modified: | 09 Jan 2012 14:29 |
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