Pradhan, Suresh K. ; Girijavallabhan, Moopil (1975) Single-electron transfer to iodides from sodium naphthalide and butyl-lithium Journal of the Chemical Society, Chemical Communications (15). pp. 591-592. ISSN 0022-4936
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1975...
Related URL: http://dx.doi.org/10.1039/C39750000591
Abstract
A non-concerted single-electron transfer pathway has been established for the reductive elimination of α-iodo epoxides to allylic alcohols with sodium naphthalide; the exchange reaction between BuLi and RI must proceed exclusively by single-electron transfer to account for identity of rates of reaction between BuLi and epimeric 3-iodo-4β,5β-epoxycholestanes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 77004 |
| Deposited On: | 09 Jan 2012 09:44 |
| Last Modified: | 09 Jan 2012 09:44 |
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