Sarkar, Sabyasachi ; Ansari, Mohammad A. (1986) Conversion of WVIOS32- into [WV2O2(µ-S)2(S2)2]2- and vice-versa by internal redox processes induced by I2 and Sx2- Journal of the Chemical Society, Chemical Communications (4). pp. 324-325. ISSN 0577-6171
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1986...
Related URL: http://dx.doi.org/10.1039/C39860000324
Abstract
Reaction of [NH4]2[WVIOS3](1) with elemental iodine in aqueous solution leads to [WV2O2(µ-S)2(S2)2]2-, isolable as the [NEt4]+ salt (2) which is converted back into (1) by Sx2-, via induced electron-transfer processes.
Item Type: | Article |
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Source: | Copyright of this article belongs to Royal Society of Chemistry. |
ID Code: | 76932 |
Deposited On: | 09 Jan 2012 03:41 |
Last Modified: | 09 Jan 2012 03:41 |
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