Thioheteroanions-unusual metal-ligand interaction and reactions

Müller, Achim ; Sarkar, Sabyasachi (1977) Thioheteroanions-unusual metal-ligand interaction and reactions Angewandte Chemie International Edition, 16 (10). pp. 705-707. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...

Related URL: http://dx.doi.org/10.1002/anie.197707051

Abstract

The first reaction products of "heteroanions" such as in (1) could now be isolated. An example is the brownish-red salt (2) which is one of the few pentacoordinate Co compounds. [(C6H5)4P]2[Co(WS4)2]+NO→[(C6H5)4P]2[Co(NO)(WS4)2]

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