Sarkar, Sabyasachi ; Mohammad, Ishaq B. ; Subramanian, Periyasamy (1985) First report of the reductive nitrosylation of tungstate(VI) by hydroxylamine. Stereospecific Synthesis of [W(NO)2Cl2(L)2] (L=py, 3-Mepy, 4-Mepy) Chemistry Letters, 14 (11). pp. 1633-1634. ISSN 0366-7022
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Official URL: http://www.journalarchive.jst.go.jp/english/jnlabs...
Related URL: http://dx.doi.org/10.1246/cl.1985.1633
Abstract
Stereospecific synthesis of cis-dichlorotrans-bis(pyridine)-cis-dinitrosyltungsten(O) and the related 3-picoline and 4-picoline derivatives have been achieved by a single pot reductive nitrosylation of sodium tungstate(VI) by hydroxylamine in the presence of excess of pyridine (or picolines) as solvent.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Chemical Society of Japan. |
| Keywords: | Preparation; Nitrosylation; Chloro Complex; Isomer; Nitrogen Heterocycle; Six Membered Ring; Transition Metal Nitrosyl Complexes; Zerovalent Metal Complexes; Organic Ligand; Acido Complex; Tungsten Nitrosyl Complexes |
| ID Code: | 76917 |
| Deposited On: | 09 Jan 2012 03:41 |
| Last Modified: | 09 Jan 2012 03:41 |
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