Asim Ansari, Mohammad ; Chandrasekaran, Jayanthi ; Sarkar, Sabyasachi (1987) Synthesis and characterization of a mononuclear Mo(IV) oxo complex (Et4N)2[MoO(S2C2(COPh)2)2] Inorganica Chimica Acta, 133 (1). pp. 133-136. ISSN 0020-1693
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0020-1693(00)84384-4
Abstract
Reaction of (Et2NH)2MoOS3 with elemental sulfur results in the formation of a known complex ion [MoO(S4)2]2-. Here, sulfur, an external oxidant, induces the electron transfer from ligated sulfur to metal. The reaction of [MoO(S4)2]2- with dibenzoyl acetylene results in the formation of a dithiolene complex ion, [MoO(S2C2(COPh)2)2] 2- having the metal in the same oxidation state. This pentacoordinated, air stable, diamagnetic compound undergoes irreversible one electron oxidation at 0.84 V and irreversible reduction at -1.76 V. The XPS data of [MoO(S4)2]2- is also discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 76914 |
| Deposited On: | 09 Jan 2012 03:41 |
| Last Modified: | 09 Jan 2012 03:41 |
Repository Staff Only: item control page
