Chaudhury, Pradeep K. ; Nagarajan, Kowliki ; Kumar, Anil ; Maiti, Rabindranath ; Das, Samar K. ; Sarkar, Sabyasachi (2003) Redox reaction between [Bu4N]2[MoVIO2 (mnt)2] and thiophenol in relevance to the autoreduction in the crystallization process of oxidized form of sulfite oxidase Indian Journal of Chemistry - Section A: Inorganic, Physical, Theoretical and Analytical Chemistry, 42 (9). pp. 2223-2227. ISSN 0376-4710
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Abstract
[Bu4N]2[MoVIO2(mnt)2] readily reacts with thiophenol leading to its reduction to [Bu4N]2 [MOIVO(mnt)2]. Detailed kinetics of this reaction is presented. The kinetics consists of three consecutive irreversible first order reactions (in the presence of excess of thiophenol) with k1, k2, k3 = 2.82(6) ´ 10-1 s-1, 6.09(5) ´ 10-2 s-1, 1.66(8) ´ 10-3 s-1 and 2.91(4) ´ 10-1 s-1, 6.15(3) ´ 10-2 s-1, 3.41(6) ´ 10-3 s-1 at 298 κ in acetonitrile and aqueous-acetonitrile media respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
| ID Code: | 76908 |
| Deposited On: | 01 Mar 2012 05:34 |
| Last Modified: | 01 Mar 2012 05:34 |
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