Benaissa, M'hamed ; Le Roux, Galo Carillo ; Joulia, Xavier ; Chaudhari, Raghunath V. ; Delmas, Henri (1996) Kinetic modeling of the hydrogenation of 1,5,9-cyclododecatriene on Pd/Al2O3 Catalyst including isomerization Industrial & Engineering Chemistry Research, 35 (7). pp. 2091-2095. ISSN 0888-5885
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ie960011u
Related URL: http://dx.doi.org/10.1021/ie960011u
Abstract
The kinetic modeling of the hydrogenation of 1,5,9-cyclododecatriene has been studied using a Pd/Al2O3 catalyst in a slurry reactor on the basis of a complete isomers analysis. A reaction scheme involving multistep hydrogenation and reversible isomerization reactions has been considered and a kinetic model of Langmuir-Hinshelwood type proposed. The kinetic parameters were estimated from experimental batch slurry reactor data. The model predictions of cyclododecene selectivity at different pressures agree well with the experimental data.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 7660 |
| Deposited On: | 25 Oct 2010 10:54 |
| Last Modified: | 30 May 2011 04:30 |
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